Deciphering key intermediates in the transformation of carbon dioxide into heterocyclic products
نویسندگان
چکیده
منابع مشابه
Transformation of carbon dioxide.
4.3. Reaction Mechanism 2373 4.4. Asymmetric Synthesis 2374 4.5. Outlook 2374 5. Alternating Polymerization of Oxiranes and CO2 2374 5.1. Reaction Outlines 2374 5.2. Catalyst 2376 5.3. Asymmetric Polymerization 2377 5.4. Immobilized Catalysts 2377 6. Synthesis of Urea and Urethane Derivatives 2378 7. Synthesis of Carboxylic Acid 2379 8. Synthesis of Esters and Lactones 2380 9. Synthesis of Isoc...
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(N-Heterocyclic-Carbene)Copper(I)-Catalyzed Carbon-Carbon Bond Formation Using Carbon Dioxide
Alkynes and olefins insert into [(IPr)CuH] 2 (IPr = N,N-bis-(2,6diisopropylphenyl)-1,3-imidazol-2-ylidene) to give copper vinyl and copper alkyl complexes. These copper complexes insert CO2 into the Cu-C bond to form copper acrylate and copper carboxylate complexes. Acrylic and carboxylic acids can be isolated
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ژورنال
عنوان ژورنال: Nature Catalysis
سال: 2018
ISSN: 2520-1158
DOI: 10.1038/s41929-018-0189-z